Cambridge 9701explain3 marks
Explain why the boiling points of the halogens increase down Group 17.
What earns the marks
“explain” means: give the reason, linking structure to the property: say what changes and why it raises the boiling point.
Three linked points: the molecules get bigger, so the instantaneous dipole–induced dipole (London) forces get stronger, so more energy is needed to separate the molecules.
- 1Down the group the molecules have more electrons (they are larger).1
- 2So the instantaneous dipole–induced dipole forces between molecules are stronger.1
- 3So more energy is needed to overcome these forces between molecules, giving a higher boiling point.1
more electronsinstantaneous dipole–induced dipolebetween moleculesmore energy to overcome
- Say “between molecules”: the forces broken on boiling are intermolecular, not covalent bonds.
- Each point should lead to the next; use “so” or “therefore”.
- Saying covalent bonds break when halogens boil.
- Writing “stronger bonds” without saying which forces.
- Mentioning only molecular mass with no link to the forces.