Paper 4 · Module
Temperature
Thermal equilibrium and temperature scales
Thermal energy flows from hotter to colder regions until they reach the same temperature: thermal equilibrium. Any property that changes with temperature (length of mercury, resistance, thermocouple e.m.f.) can make a thermometer, but different properties don't agree between fixed points. The thermodynamic scale doesn't depend on any substance: its zero is absolute zero, and .
≈ 30 minSpecific heat capacity and latent heat
Specific heat capacity is the energy needed per unit mass per unit temperature rise: . Water's is about J kg⁻¹ K⁻¹. Specific latent heat is the energy needed per unit mass to change state at constant temperature: . Vaporisation needs much more energy than melting because molecules must be completely separated and push back the atmosphere.
≈ 35 min