Heating makes particles move faster and push further apart, so most materials expand: gases most, liquids less, solids least. Heating also raises the internal energy. The energy needed for a temperature rise depends on the mass and the material: ΔE=mcΔθ, where c is the specific heat capacity.
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Section 1 of 14
Learning objectives
Describe thermal expansion and give uses and problems it causes.
Explain the order of expansion of gases, liquids and solids.
Use ΔE=mcΔθ to find energy, mass, c or temperature change.
Describe an experiment to measure specific heat capacity.
Pause and think
On a hot beach, sand burns your feet but the sea feels cool, even though the Sun shines equally on both. Why?
Section 2 of 14
Core idea
Start hereHot sand, cool sea
On a sunny day the sand burns your feet while the sea stays cool, though both get the same sunshine. Water needs far more energy to warm up by each degree. That property is its specific heat capacity.
The big idea
E=mcΔθ, c in J/kg °C. Most materials expand when heated.
1. Specific heat capacity
Heating 1 kg of water and 1 kg of aluminium with the same heaterWater needs much more energy per degree, so it heats up slowly and cools slowly. That is why it is used in radiators and why coastal climates are milder.
E=mcΔθ
where
E
energy supplied (J).
m
mass (kg).
c
specific heat capacity (J/kg °C).
Δθ
temperature change (°C).
Worked exampleWater vs aluminium
Warm 1 kg of each by 20 °C (c=4200, 900).
Goal
Energies.
Strategy
Formula.
1
1×4200×20=84000 J
Water.
2
1×900×20=18000 J
Aluminium.
Answer84 kJ vs 18 kJ.
✓ CheckRatio 4200/900=4.7 ✓: why water stores heat well.
Worked exampleMeasuring c
50 W heater for 5 min warms 0.5 kg of oil by 15 °C.
Goal
c.
Strategy
E=Pt, then rearrange.
1
E=50×300=15000 J
5 min = 300 s.
2
c=0.5×1515000=2000
Rearrange.
Answer2000 J/kg °C.
✓ CheckHeat lost to the room makes this an overestimate ✓.
⚠️ Common misconceptionMinutesPower × time needs time in seconds.
2. Thermal expansion
Gaps in railway lines and sagging power cables allow for expansionWithout gaps, hot rails would buckle. A bimetallic strip (two metals expanding by different amounts) bends when heated and is used in thermostats.
Particles vibrate more and push slightly apart.
Gases expand most, then liquids, then solids.
Uses: thermometers, bimetallic strips.
Pause and think
Why do bridges have expansion joints?
Summary
E=mcΔθ.
Expansion: allow gaps.
Key words
Specific heat capacity
Energy to raise 1 kg by 1 °C.
📜 HistoryBlack and "latent" heat.Joseph Black, a Scottish chemist, noticed in the 1760s that equal masses of different substances needed different amounts of heat for the same temperature rise. His idea of "heat capacity" separated temperature (how hot) from heat (how much energy).
🤯 Fun factThe Eiffel Tower grows in summer.The Eiffel Tower is about 15 cm taller on a hot summer day than on a cold winter one, because its 7300 tonnes of iron expand with heat.
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