Paper 3B · Module
Thermodynamics and engines
The first law of thermodynamics
The first law is conservation of energy for a system: , where is the energy transferred to the system by heating and is the work done on the system. When a gas expands at constant pressure, it does work on its surroundings, so . On a – graph, work is the area under the curve.
≈ 40 minHeat engines and heat pumps
The first law tracks energy in a gas. Isothermal changes keep constant; adiabatic changes () keep constant. Work done is the area under a p–V curve, so the area enclosed by a cycle is the net work per cycle. No engine can turn all heat into work: maximum efficiency is . Heat pumps and refrigerators run engines backwards.
≈ 50 min